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Polymerisation

Monomers

Organic compounds are typically composed of recurring subunits (monomers) which are covalently joined to form polymers

  • The monomeric subunit of carbohydrates is a monosaccharide (single sugar unit)

  • Nucleic acids are composed of repeating nucleotides (containing a sugar, phosphate and nitrogenous base)

  • Proteins consist of linked chains of amino acids which differ according to a variable side chain (‘R’ group)

  • Lipids do not contain monomers but certain types may be composed of distinct subunits (fatty acid chains)

Types of Monomers / Subunits
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Monosaccharide

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Fatty Acid

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Nucleotide

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Amino Acid

Polymerisation

Polymers can be formed from monomeric subunits via condensation reactions

  • A hydroxyl group (-OH) on one monomer is combined with a hydrogen atom (-H) on another monomer 

  • The two monomers become covalently bonded and a water molecule is produced as a by-product

Condensation Reaction
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Condensation Reaction
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Polymers

Polymers are large macromolecules composed of smaller repeating subunits (called monomers) via condensation reactions

  • Carbohydrates: Monosaccharides are joined together to form polysaccharides via glycosidic linkages

  • Nucleic Acids: Nucleotides are connected by phosphodiester bonds to form polynucleotide chains (DNA or RNA)

  • Proteins: Amino acids are linked by peptide bonds to form polypeptide chains (proteins can possess multiple chains)

  • Lipids: Do not possess monomers but fatty acid chains can be connected by ester linkages to form triglycerides and phospholipids

Types of Polymers
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Carbohydrates
fat%20polymer
Lipids*
nucleic%20polymer
Nucleic Acids
protein%20polymer
Proteins
Digestion

Polymers can be broken down into their monomeric subunits via hydrolysis reactions

  • A water molecule is split to provide the -H and -OH groups required to break the covalent bond between two monomers

Hydrolysis Reaction
glycocalyx
Hydrolysis Reaction
glycocalyx